Surely you’re joking. Polya pioneered so much combinatorics I don’t even know where to begin. Heck, a lot of counting problems reduces to polya’s enumeration theorem. The page of “references” to stuff named after him should be a clue to you.
Definitely. Whatever one may think of "How to Solve It," Polya was a renowned mathematician. The book is like the Richard Hamming lectures that often come up on HN: Great thoughts from a great mind but not easily applied by the average or even above average Joe.