The common understanding seems to be that producing true LK99 is very difficult as you need to get the crystal structure just right. Many samples probably have mixes of the correct and other structures. That's why some float and some don't. The sample might be quite "dirty", meaning the critical temperature is lower.
Seems like it may depend on getting specific binding sites.
> Finally, the calculations presented here suggest that Cu substitution on the appropriate (Pb(1)) site displays many key characteristics for high-TC superconductivity, namely a particularly flat isolated d-manifold, and the potential presence of fluctuating magnetism, charge and phonons. However, substitution on the other Pb(2) does not appear to have such sought-after properties, despite being the lower-energy substitution site. This result hints to the synthesis challenge in obtaining Cu substituted on the appropriate site for obtaining a bulk superconducting sample. [1]
