If they're just an employee then you can argue "who cares" but also "why not?". If they're offered any options I'd say yes they should ask.
By definition, the CEO is issuing stock in lieu of money.
They are issuing a chance at very large future compensation (say 10% chance at 12x) in lieu of current cold cash (100% chance of 1x).
The CEO is not in the driver's seat, otherwise they wouldn't issue stock.
NOTE: This is a totally different thing than stock incentive programs.
If they're just an employee then you can argue "who cares" but also "why not?". If they're offered any options I'd say yes they should ask.