Considering this is only for FedRAMP Low/Medium, I'm not sure why any contractor or agency would pick this over AWS GovCloud, where finding people already familiar with the platform is easy.
I haven't used AWS's version, but the gov version of Azure is terrible. Missing so many features and limited in so many ways and there are so many "gotchas". And no matter how many times you tell a vendor that's what you have they won't admit their product isn't compatible until the second or third time they try to implement.
I worked on government projects at Azure for years. Their US Government cloud is a second-class citizen. Getting the average engineer to care about problems with their their offerings in government clouds relative to the commercial cloud is like pulling teeth.
There are different levels at the infra/platform/application layer. cloud.gov is built on top of AWS IaaS (though the PaaS could also be deployed on other infra).