Yeah, if it really does deliver ~25ms latency and up to 1GBPS, work from anywhere becomes much more literal. Currently a lot of remote work and things like multiplayer games are limited to areas with reliable broadband.
But if you can get that anywhere... it'll be amazing and have a profound effect.
v2 most likely. The currently launched satellites do not have cross-satellite links so the satellites can only provide service while they are within range of a ground station. The cross satellite links were originally planned for v1 but are behind schedule and nobody outside SpaceX knows what the current schedule is.
I don't know anything specific a out starlink, but I have hundreds of days of experience trying to hit iridium sattelites while hiking in the wild. You need direct line-of-sight to sky.
But if you can get that anywhere... it'll be amazing and have a profound effect.