I have been using XML Starlet (http://xmlstar.sourceforge.net/) for many years in combination with Unix Shell. It is a very nice command line tool allowing to extract data from XML documents (using XPath expressions), to edit XML documents and even to convert XML to PYX format. The only problem it has so far is with big XML files as it loads them in the memory. But there is work going on to allow extract data without loading whole XML file in RAM.