> Why Mauna Loa? Early attempts to measure CO2 in the USA and Scandinavia found that the readings varied a lot due to the influence of growing plants and the exhaust from motors. Mauna Loa is ideal because it is so remote from big population centres. Also, on tropical islands at night, the prevailing winds blow from the land out to sea, which effect brings clean, well-mixed Central Pacific air from high in the atmosphere to the observatory. This removes any interference coming from the vegetation lower down on the island.
> But how about gas from the volcano? It is true that volcanoes blow out CO2 from time to time and that this can interfere with the readings. Most of the time, though, the prevailing winds blow the volcanic gasses away from the observatory. But when the winds do sometimes blow from active vents towards the observatory, the influence from the volcano is obvious on the normally consistent records and any dubious readings can be easily spotted and edited out.